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Solid-Phase Synthesis and Encoding Strategies for Olefin Polymerization Catalyst Libraries
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1998
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EngineeringOrganic ChemistryChemistryPolymersChemical EngineeringOrganometallic CatalysisActive Polymerization CatalystsPolymer ChemistryMaterials ScienceInorganic ChemistryCatalyst LibraryCatalysisOrganometallic PolymerCatalytic SynthesisFluorescent MarkersPolymer ScienceEncoding StrategiesPolymerization KineticsPolymer ReactionPolymer Synthesis
Active polymerization catalysts, novel resin-bound diimine complexes of nickel(II) and palladium(II) are obtained by combinatorial synthesis and combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage of the tag from the polymer-coated resin, HPLC can be used to determine the pathway along which the products were formed.