Structure and Room-Temperature Ferromagnetism of Zn-Doped SnO₂ Nanorods Prepared by Solvothermal Method

Abstract

Sn 1− x Zn x O 2 nanorods with nanoflower morphology have been synthesized by a solvothermal method. The concentration of Zn dopants is found to play an important role in tuning the morphology, size, and structure of the Sn 1− x Zn x O 2 nanorods. The local structure study through X-ray absorption fine structure spectroscopy reveals that the Zn atoms have successfully substituted for Sn sites in SnO 2 lattice without forming secondary phases. The comparison of experimental X-ray absorption near-edge structure spectra with simulated results shows that the substitutional doping of Zn creates numerous oxygen vacancy and Sn vacancy ( V Sn ) defects in the structure. The synthesized nonmagnetic Zn ions doped SnO 2 nanorods exhibit obvious room-temperature ferromagnetism, and their saturated magnetic moment is sensitive to the concentration of Zn dopants. Based on d 0 ferromagnetism, the observed ferromagnetic ordering of the Sn 1− x Zn x O 2 nanorods could be related to the doping-induced V Sn defects.