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An efficient and stereoselective synthesisi of homoallylic alcohols via nickel-catalysed coupling of 5-alkyl-2,3-dihydrofurans with Grignard reagents
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1987
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Cross-coupling ReactionEngineeringStereoselective SynthesisiGrignard ReagentsStereoselective MethodOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryHomoallylic AlcoholsAsymmetric CatalysisEnantioselective SynthesisCatalytic Synthesis
The low-valent nickel-catalysed coupling of Grignard reagents with 5-alkyl-2,3-dihydrofurans is an efficient and stereoselective method for synthesising homoallylic alcohols provided appropriate care is taken in the workup.