High‐Spin Wheel of a Heptanuclear Mixed‐Valent Fe<sup>II,III</sup> Complex

Hiroki Oshio, Norihisa Hoshino, Tasuku Ito, Motohiro Nakano, Franz Renz, Philipp Gütlich

Angewandte Chemie International Edition · 2003 · 107 citations · 29 references

Concepts

Abstract

Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron(II) chloride, and subsequent oxidation with [(tBu4N)MnO4] yielded a heptanuclear mixed-valent iron wheel (see picture) with a spin ground state of S=29/2.

References

29