A convenient, one-step, high-yield replacement of an anomeric hydroxyl group by a fluorine atom using dast. Preparation of glycosyl fluorides.

AN EFFICIENT METHOD FOR GLUCOSYLATION OF HYDROXY COMPOUNDS USING GLUCOPYRANOSYL FLUORIDE

Teruaki Mukaiyama, Yoshiyuki Murai, Shin‐ichiro Shoda · Chemistry Letters · 1981 · 410 citations

Bioorganic Chemistry, Glycosylation, Biochemistry +14

Practical synthesis of oligosaccharides. Partial synthesis of avermectin B1a

K. C. Nicolaou, Roland E. Dolle, Demetris P. Papahatjis · Journal of the American Chemical Society · 1984 · 311 citations

Bioorganic Chemistry, Partial Synthesis, Biochemistry +10

Glycosylation using glucopyranosyl fluorides and silicon-based catalysts. Solvent dependency of the stereoselection

Shun-ichi Hashimoto, Masahiko Hayashi, Ryōji Noyori · Tetrahedron Letters · 1984 · 290 citations

Bioorganic Chemistry, Engineering, Natural Sciences +13

STEREOSELECTIVE SYNTHESIS OF 1,2-<i>CIS</i>-GLYCOFURANOSIDES USING GLYCOFURANOSYL FLUORIDES

Teruaki Mukaiyama, Yukihiko Hashimoto, Shin‐ichiro Shoda · Chemistry Letters · 1983 · 104 citations

Bioorganic Chemistry, Biochemistry, Natural Sciences +10

A novel procedure for C-glycosylation involving Lewis acid-catalyzed coupling-reactions of glycosyl fluorides with enol trimethylsilyl ethers

Younosuke Araki, Kazuko Watanabe, Fu-Hua Kuan et al. · Carbohydrate Research · 1984 · 52 citations

Asymmetric Catalysis, Cross-coupling Reaction, Engineering +9