Publication | Closed Access
Interaction of NO with the MgO(100) Surface Studied by Infrared Reflection Absorption Spectroscopy
15
Citations
11
References
2002
Year
EngineeringAbsorption SpectroscopyChemistrySpectroscopic PropertyDimer FormationOptical PropertiesThin Film ProcessingMaterials ScienceOxide HeterostructuresDimeric NoOxide ElectronicsPhysical ChemistryLayered MaterialSurface CharacterizationMaterial AnalysisNatural SciencesSpectroscopySurface ScienceApplied PhysicsCondensed Matter PhysicsMagnesium-based CompositeSurface AnalysisThin Films
Infrared reflection absorption spectroscopy (IRAS) at low temperatures (ca. 40 K) has been used to study the interaction of NO with highly ordered MgO(100) thin films. Dimer formation has been observed in the multilayer regime at (<60 K) and in the monolayer regime at 60−70 K. Using 15NO, it is shown that dimeric NO, (NO)2, is the key intermediate in the formation of N2O above 70 K.
| Year | Citations | |
|---|---|---|
Page 1
Page 1