Pressure and temperature‐dependent quantum yields for the photodissociation of acetone between 279 and 327.5 nm

Abstract

The photodissociation of acetone has been studied over the wavelength (λ) range 279–327.5 nm as a function of temperature ( T ) and pressure ( p ) using a spectroscopic method to monitor the acetyl (CH 3 CO) radical fragment. Above 310 nm the quantum yield (QY) is substantially smaller than previous measurements, and decreases with T . The QYs for production of CH 3 CO + CH 3 and CH 3 + CH 3 + CO have been parameterised as a function of λ, p and T and used to calculate the altitude dependence of the photolysis frequency. In the upper troposphere (UT) the acetone photolysis lifetime is a factor of 2.5–10 longer, dependent upon latitude and season, than if the previously recommended QYs are used.