Circular dichroism in photoelectron angular distributions from two-color (1+1) REMPI of NO

Abstract

A detailed experimental and theoretical study of dichroic effects in photoelectron angular distributions is reported for (1+1), two-color REMPI of NO via the A 2Σ+, v=0 state. Optically aligned A state rotational levels are probed through ionization by circularly polarized light. Resultant photoelectron angular distributions exhibit significant left–right asymmetry, the phase and magnitude of which are shown to be related to the curvature of the excited state MJ distribution. Theoretical calculations involving a full ab initio treatment of the ionization dynamics result in circularly dichroic angular distribution (CDAD) parameters in good agreement with those derived experimentally. Additional effects including hyperfine depolarization and coherence are also discussed in relation to the observed CDAD data.