Concepedia

Ferrous Fe(II) hydration in a 1 molal heavy water solution of iron chloride

G J Herdman, G. W. Neilson

Journal of Physics Condensed Matter · 1992 · 38 citations · 10 references

DOI

Concepts

Abstract

The first-order isotopic difference method of neutron diffraction was applied to the iron ions of an acidic 1 molal solution of iron chloride in heavy water. Results were obtained for the Fe2+ hydration; these show that this ion is hexahydrated with nearest neighbour Fe. . .O and Fe. . .D distances of 2.12(2)AA and 2.75(5)AA, respectively. There is also evidence of a weak second hydration shell.

References

10

X-Ray Diffraction Studies of the Structures of Hydrated Divalent Transition-Metal Ions in Aqueous Solution

Hitoshi Ohtaki, Toshio Yamaguchi, Masunobu Maeda · Bulletin of the Chemical Society of Japan · 1976 · 225 citations

, , +12

The structure of an aqueous solution of nickel chloride

G. W. Neilson, J. E. Enderby · Proceedings of the Royal Society of London A Mathematical and Physical Sciences · 1983 · 115 citations

, , +14

Structure of hexaaquairon(III) nitrate trihydrate. Comparison of iron(II) and iron(III) bond lengths in high-spin octahedral environments

N. J. Hair, James K. Beattie · Inorganic Chemistry · 1977 · 83 citations

, , +10

Structure and dynamic behavior of transition-metal ions in aqueous solution: an EXAFS study of electron-exchange reactions

T. K. Sham, J. B. Hastings, M. L. Perlman · Journal of the American Chemical Society · 1980 · 82 citations

, , +14

On the crystal chemistry of salt hydrates. III. The determination of the crystal structure of FeSO<sub>4</sub>.7H<sub>2</sub>O (melanterite)

W. H. Baur · Acta Crystallographica · 1964 · 80 citations · Full text

, , +16