Proceedings of the Royal Society of London A Mathematical and Physical Sciences · 1983 · 115 citations · 3 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistryPhysical ChemistryCoordination ChemistryCrystal ChemistryNeutron DiffractionSolution ChemistryX-ray CrystallographyChloride ChemistryMetal Ion ChemistryNeutron Diffraction Phase AnalysisNickel ChemistryPowder Neutron DiffractionReal-space Refinement
Abstract The method of multipattern analysis based on neutron diffraction from isotopically different samples has been applied to a 4.35 molal solution of NiCl2 in D2O. Seven distinct scattering patterns were obtained at a temperature of 21 °C and the particle-particle pair functions for correlations between Cl- and D2O, Ni2+ and D2O, Cl- and Cl-, Ni2+ and Ni2+ and Ni2+ and Cl- were extracted from the data. The results are used to obtain a real-space description of the ions and their immediate environment.
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The structure of molten sodium chloride
F G Edwards, J. E. Enderby, R A Howe et al. · Journal of Physics C Solid State Physics · 1975 · 260 citations
Chloride ions in aqueous solutions
S. Cummings, J. E. Enderby, G. W. Neilson et al. · Nature · 1980 · 141 citations