Concepedia

Alkenyldimethyl(2-thienyl)silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-Coupling Reaction

Kazushi Hosoi, Kyoko Nozaki, Tamejiro Hiyama

Chemistry Letters · 2002 · 58 citations · 11 references

DOI

Concepts

Abstract

Abstract Introduction of a 2-thienyl group to the silicon atom of alkenylsilanes promoted the cross-coupling reaction with aryl halides mediated by tetrabutylammonium fluoride and a palladium catalyst. The reaction proceeded under extremely mild conditions to afford arylalkenes in high yields.

References

11

The Palladium‐Catalyzed Cross‐Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods (58)]

J. K. Stille · Angewandte Chemie International Edition in English · 1986 · 3.4K citations

, , +9

Hydrosilylation of 1-hexyne catalyzed by rhodium and cobalt-rhodium mixed-metal complexes. Mechanism of apparent trans addition

Iwao Ojima, Núria Clos, Robert J. Donovan et al. · Organometallics · 1990 · 267 citations

, , +11

Highly Stereospecific, Cross-Coupling Reactions of Alkenylsilacyclobutanes

Scott E. Denmark, Jun Young Choi · Journal of the American Chemical Society · 1999 · 194 citations

, , +9

A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)]

G. Chandra, Peter Y. Lo, Peter B. Hitchcock et al. · Organometallics · 1987 · 185 citations

, , +13

Diversity-Oriented Synthesis of Multisubstituted Olefins through the Sequential Integration of Palladium-Catalyzed Cross-Coupling Reactions. 2-Pyridyldimethyl(vinyl)silane as a Versatile Platform for Olefin Synthesis

Kenichiro Itami, Toshiki Nokami, Yoji Ishimura et al. · Journal of the American Chemical Society · 2001 · 176 citations

, , +14