Magnetic Order–Order Transition in Tetragonal ErB₂C₂

Abstract

We have investigated magnetic properties of ErB 2 C 2 which is an isostructural compound of the antiferroquadrupolar ordering materials, DyB 2 C 2 and HoB 2 C 2 , by magnetisation and neutron diffraction measurements. ErB 2 C 2 shows magnetic transitions at T N = 15.9 K and T t = 13.0 K. The magnetic structure of the ground state is a simple Ising-type antiferromagnetic one with a propagation vector of k =(1, 0, 0). The intermediate phase between T N and T t under zero magnetic field is a long range magnetic ordered state with a transverse sinusoidal modulation with a propagation vector of (1+δ, δ, 0), where δ=0.1120(2) which is nearly the same as that in phase IV in HoB 2 C 2 .