Publication | Closed Access
Heck Couplings at Room Temperature in Nanometer Aqueous Micelles
179
Citations
21
References
2008
Year
Room TemperatureEngineeringNatural SciencesMolecular BiologyMicellePhysical ChemistryOrganic ChemistryHeck Cross-couplingsMolecular AggregateTriton X-100ChemistryHeck CouplingsBiomolecular EngineeringHost-guest Chemistry
A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. These are the first examples of Heck reactions conducted in water (as the only solvent) at room temperature.
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