Publication | Closed Access
Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application
66
Citations
33
References
2011
Year
Hydrogen Energy TechnologyEngineeringPorous PolymerChemistryBorophenePolymersChemical EngineeringBoron TrihalidesHydrogen Storage ApplicationHybrid MaterialsPolymer ChemistryMaterials ScienceChemisorptionAdsorptionHydrogenPorous Borazine-linked PolymersPorous CarbonPolymer ScienceNew ClassOrganic-inorganic Hybrid Material
A new class of highly porous borazine-linked polymers (BLPs) has been synthesized utilizing arylamines and boron trihalides. BLPs exhibit Brunauer–Emmett–Teller (BET) surface areas in the range of 503 to 1364 m2 g−1 and store up to 1.3 wt% of hydrogen with 7.1 kJ mol−1 isosteric heat of adsorption.
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