Angewandte Chemie International Edition · 2008 · 2.6K citations · 18 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOrganic ChemistryPolymer ChemistryCoordination PolymersInorganic MaterialsPorous MaterialsCatalyst SupportsGas StorageGas Storage MaterialsMicroporous MaterialsOrganic-inorganic Hybrid Materials
Ordered and amorphous microporous polytriazine networks have been obtained from the trimerization of nitriles in a ZnCl2 melt at 400 °C (see structure of the polymer formed from 1,4-dicyanobenzene; C gray, N blue). The materials are high-performance polymers with very large surface areas and could find applications in gas storage, as sensors, or catalyst supports.
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Porous, Crystalline, Covalent Organic Frameworks
Adrien P. Côté, Annabelle I. Benin, N.W. Ockwig et al. · Science · 2005 · 8.1K citations
Designed Synthesis of 3D Covalent Organic Frameworks
Hani M. El‐Kaderi, Joseph R. Hunt, José L. Mendoza-Cortés et al. · Science · 2007 · 2.5K citations
Conjugated Microporous Poly(aryleneethynylene) Networks
Jia‐Xing Jiang, Fabing Su, Abbie Trewin et al. · Angewandte Chemie International Edition · 2007 · 1.5K citations