Journal of the Physical Society of Japan · 2005 · 11 citations · 12 references
Natural SciencesPhysicsAtomic PhysicsPhysical ChemistrySpectroscopyAb Initio MethodsFine StructureClose-coupling CalculationsElectron Excitation ProcessesElectron-electron InteractionsElectron-impact ExcitationFine Structure TransitionsForbidden TransitionsHydrogenic Energy Levels
The electron-impact transitions between the n =2 fine-structure levels of hydrogenic ions are calculated by an improved close coupling scheme that accounts for the electron-exchange effect. It is found that the electron-exchange effect is relatively unimportant in the optically allowed transitions, as expected from its long-range nature, but represents a considerable contribution to the cross-sections of the optically forbidden transitions, where the contribution of low partial waves is more significant. Hence, a close coupling calculation including the exchange effect is required for low partial waves.
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