Synthesis and Characterization of Truncated Triangular Silver Nanoplates

Abstract

Truncated triangular silver nanoplates have been synthesized in large quantities using a solution phase method in the presence of cetyltrimethylammonium bromide micelles. The obtained particles have an average edge size of 68 nm, thickness of 24 nm, and the degree of truncation of 0.35. They are single crystals, with a (111) lattice plane as the basal plane. The aqueous solution of these particles displays a clear red color due to a strong in-plane dipole plasmon resonance peaked at 552 nm. These particles can self-assemble into chainlike nanostructures through either partial or close stacking of neighborhood nanoplates.