Characterization of defect-related optical absorption in ZnGeP2

Abstract

A broad optical absorption band with a peak near 1 μm is present in most single crystals of ZnGeP2. These same crystals have an electron paramagnetic resonance (EPR) signal which has been assigned to singly ionized zinc vacancies. A direct correlation between the intensity of the optical absorption at 1 μm and the intensity of the EPR signal has been established using a set of ZnGeP2 crystals where this absorption varied widely. These results suggest that the singly ionized zinc vacancy acceptor plays a direct role in the electronic transition(s) responsible for the 1 μm optical absorption. In separate experiments, it was found that illuminating the ZnGeP2 crystals with a He–Ne laser (632.8 nm) while at temperatures near 25 K produces an increase in the absorption at 1 μm and an increase in the zinc vacancy EPR spectrum. These latter results provide further evidence that the absorption at 1 μm is associated with the singly ionized zinc vacancy acceptor.