Concepedia

The photodissociation threshold of NO2: Precise determination of its energy and density of states

R. Jost, Jesper Nygård, Adam Pasinski, Antoine Delon

The Journal of Chemical Physics · 1996 · 89 citations · 24 references

DOI

Concepts

Abstract

The NO2 photodissociation threshold has been observed by laser induced fluorescence in a jet at 25 128.57±0.05 cm−1. The unexpected high vibronic level density of 2.7 levels/cm−1 is tentatively attributed to long range interactions between the NO (2Π1/2) and O(3P2) products. The energy spacing and intensity distributions indicate rovibronic chaos.

References

24

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THE ABSORPTION SPECTRUM OF NO<sub>2</sub> IN THE 3 700–4 600 Å REGION

A. E. Douglas, Klaus Huber · Canadian Journal of Physics · 1965 · 197 citations

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The Entropies of Nitrogen Tetroxide and Nitrogen Dioxide. The Heat Capacity from 15°K to the Boiling Point. The Heat of Vaporization and Vapor Pressure. The Equilibria N2O4=2NO2=2NO+O2

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The β and γ bands of nitric oxide observed during the flash photolysis of nitrosyl chloride

Rolf Engleman, Prince E. Rouse · Journal of Molecular Spectroscopy · 1971 · 144 citations

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NO2 jet cooled visible excitation spectrum: Vibronic chaos induced by the <i>X</i> 2<i>A</i>1–<i>A</i> 2<i>B</i>2 interaction

Antoine Delon, R. Jost, M. Lombardi · The Journal of Chemical Physics · 1991 · 130 citations · Full text

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