The preparation of a hexacyclic intermediate for the synthesis of strychnos alkaloids

Protection of hydroxyl groups as tert-butyldimethylsilyl derivatives

E. J. Corey, A. Venkateswarlu · Journal of the American Chemical Society · 1972 · 1.8K citations

Natural Sciences, Chemistry, Analytical Chemistry +6

Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers

Yoshihiko Ito, Toshikazu Hirao, Takeo Saegusa · The Journal of Organic Chemistry · 1978 · 861 citations

Natural Sciences, Chemistry, Catalysis +5

Chemistry of organosilicon compounds. 99. Conjugate addition of allylsilanes to .alpha.,.beta.-enones. A New method of stereoselective introduction of the angular allyl group in fused cyclic .alpha.,.beta.-enones

Akíra Hosomi, Hideki Sakurai · Journal of the American Chemical Society · 1977 · 344 citations

Natural Sciences, Chemistry, Organic Chemistry +8

THE TOTAL SYNTHESIS OF STRYCHNINE

R. B. Woodward, Michael P. Cava, W. David Ollis et al. · Journal of the American Chemical Society · 1954 · 316 citations

Pharmacy, Chemistry, Medicinal Chemistry +6

Iodotrimethylsilane—a versatile synthetic reagent

George A. Olah, Subhash C. Narang · Tetrahedron · 1982 · 300 citations

Natural Sciences, Chemistry, Organic Chemistry +4