Chemical Communications · 1998 · 31 citations · 11 references
Lithium ThiophenolateEngineeringBiochemistryThiolate AnionNatural SciencesOrganic ChemistryCondensation AdductStereoselective SynthesisChemistryHigh Syn-selectivityPharmacologyAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
A combination of a tert-butyl α,β-unsaturated ester, an aldehyde and lithium thiophenolate in CH2Cl2 undergoes a one-pot Michael/aldol tandem reaction to give a condensation adduct of the three components, an α-phenylthiomethyl-β-hydroxy ester, in good yield with high syn-selectivity.
11
Modern organoselenium chemistry
Derrick L. J. Clive · Tetrahedron · 1978 · 473 citations
Organic Chemistry, Modern Organoselenium Chemistry, Main Group Chemistry +1
Akira Itoh, Shuji Ozawa, Koichiro Oshima et al. · Tetrahedron Letters · 1980 · 92 citations
Organic Chemistry, 1-Acylethenyl Anion Equivalent, Stereoselective Synthesis +5