Physical Review A · 2010 · 27 citations · 42 references
Natural SciencesChemistryPhysicsComputational ChemistryMolecular PhysicsSpectroscopyAb Initio MethodsCross Section DataMolecular ScatteringMolecular SpectroscopyNuclear Cross SectionsScattering TheoryElectron Cross SectionsFuran ChemistryIntegral Cross SectionIonization Cross SectionsMolecular Cross SectionScattering Cross Section MeasurementScattering Cross SectionsTotal Cross Sections
Electron-scattering cross sections have been determined for the furan (C${}_{4}$H${}_{4}$O) molecule, both experimentally and theoretically. An absolute total cross section (TCS) has been measured over energies from 0.6 to 400 eV using a linear electron-transmission method. The TCS energy function is dominated with a very broad enhancement, between 1.2 and 9 eV; on the low-energy side, some resonant structures are visible. Integral elastic (ECS) and ionization (ICS) cross sections have been also calculated up to 4 keV in the additivity rule approximation and the binary-encounter-Bethe approach, respectively. Their sum, ECS$+$ICS, is in a very good agreement with the measured TCS above 70 eV.
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Natural Sciences, Chemistry, Physics +13