Proceedings of the Royal Society of London A Mathematical and Physical Sciences · 1976 · 55 citations · 22 references
Natural SciencesChemistryPhysicsMolecular PhysicsQuantum MechanicsSpectroscopyAb Initio MethodsAbsorption SpectroscopyAtomic SpectraAtomic TransitionsElectronic SpectroscopyAbsorption SpectraAtomic Line SpectraElectronic Absorption SpectraExtreme Ultraviolet SpectroscopyHartree-fock ApproximationQuantum DefectsUltraviolet Absorption FeaturesUltraviolet Absorption Lines
Abstract The Ca I absorption spectrum has been photographed between 10 and 120 Å for the first time. At least seven discrete features – all attributable to excitation of the 2p subshell – have been observed. Identifications are made by comparison with Hartree–Fock calculations. The Hartree–Fock results also support an explanation of the irregular quantum defects and remarkable breadths of the lines assigned to the 2p→3d transition.
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Effects of Configuration Interaction on Intensities and Phase Shifts
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