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Versatile Modes of Allene Bonding in the Structures of [W<sub>2</sub>(O<i>t</i>Bu)<sub>6</sub>(C<sub>3</sub>H<sub>4</sub>)], [W<sub>2</sub>(O<i>t</i>Bu)<sub>6</sub>(C<sub>3</sub>H<sub>4</sub>)(CO)<sub>2</sub>], and [W<sub>2</sub>(O<i>t</i>Bu)<sub>6</sub>(C<sub>3</sub>H<sub>4</sub>)<sub>2</sub>]
27
Citations
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References
1989
Year
Materials ScienceInorganic ChemistryAllene BondingAllene MoietyEngineeringW2 CenterNatural SciencesChemical BondCoordination ComplexHydrogen BondMolecular ComplexQuantum ChemistryChemistryVersatile ModesElectronic StructureInorganic SynthesisComplex 1Inorganic Compound
The allene moiety and the W2 center in the complex 1 are parallel—this coordination is unprecedented. Addition of CO or allene to 1 yields the two other title compounds, respectively, in which an allene is η1,η3-bonded and two CO groups or an additional η2-C3H4 ligand (see formula on the right) is present.
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