The Journal of Chemical Physics · 1960 · 59 citations · 2 references
Natural SciencesChemistryPhysicsInorganic ChemistryPhysical ChemistrySpectroscopyCoordination ChemistryInorganic SpectroscopyMetal-ligand BondingOptical SpectroscopyRaman SpectroscopyTransition Metal ComplexesRaman SpectraRaman Spectral InterpretationVibrational Spectroscopy Of Metal-ligand Bonds
The Raman spectra of solutions containing cuprous, argentous, and mercuric ions together with cyanide ions indicate the presence of the di-, tri-, and tetra-coordinated complexes. The spectra from solutions containing zinc and cadmium ions, respectively, with cyanide ions could be investigated in concentrations where only the tetra-coordinated complex is observed.
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