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The First Decaisopropylmetallocene: One‐Pot Synthesis of [Rh(C<sub>5</sub><i>i</i>Pr<sub>5</sub>)<sub>2</sub>]PF<sub>6</sub> from [Rh(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>]PF<sub>6</sub> by Formation of 20 Carbon–Carbon Bonds
32
Citations
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References
1994
Year
Materials ScienceInorganic ChemistryChemical EngineeringCarbon–carbon BondsEngineeringCoordination ComplexCorresponding Rhodium ComplexOrganic ChemistryFirst DecaisopropylmetalloceneOrganometallic CatalysisCobalt Sandwich ComplexChemistryOne‐pot SynthesisSecond-row Transition MetalSynthetic ChemistryInorganic SynthesisInorganic Compound
Only with a second-row transition metal as the central atom can decamethylmetallocenes [M(C5Me5)2]+ be fully permethylated to give decaisopropylmetallocenes 1. The corresponding rhodium complex, M = Rh, was isolated in 55% yield; in the analogous reaction of the cobalt sandwich complex, a maximum of 14 methyl groups were introduced.
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