Publication | Closed Access
Ultimate diastereoselectivity in the ring closure of photochromic diarylethene possessing facial chirality
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Citations
47
References
2010
Year
Materials ScienceRing ClosureThiophene RingOrganic Charge-transfer CompoundEngineeringOrganic Material ChemistryPhotochemistryUv-light IrradiationFacial ChiralityOrganic ChemistryOrganometallic PolymerChemistrySupramolecular PhotochemistryTriethyleneglycol BridgePhotochromismBiophysicsUltimate Diastereoselectivity
A bisthienylethene with hitherto unprecedented facial chirality imposed by a triethyleneglycol bridge on a thiophene ring was synthesized and its photochromic ring closure was shown to occur with 100% diastereoselectivity upon UV-light irradiation.
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