Journal of the American Chemical Society · 2006 · 61 citations · 16 references
Natural SciencesChemistryMagnetic MaterialsNuclear ChemistrySpectroscopyElectron Paramagnetic ResonanceHyperfine StructureLanthanide ChemistryMagnetic Resonance SpectroscopyMetal-carbon BondingMolecular StructureFull AssignmentLanthanide BondingLanthanide SpectroscopyParamagnetic CentersParamagnetic Nmr SpectroscopyTwo-dimensional Nmr Spectroscopy
The mapping of bond connectivity in the carbon cage of [Ce@C82]- and full assignment of the NMR lines were successfully achieved by means of 2D INADEQUATE NMR measurement. Paramagnetic NMR analysis shows that the Ce atom in [Ce@C82]- is located at an off-centered position adjacent to a hexagonal ring along the C2 axis of the C2v-C82 cage.
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Y. Chai, Ting Guo, C. Jin et al. · The Journal of Physical Chemistry · 1991 · 1.3K citations
Confirmation by X-ray diffraction of the endohedral nature of the metallofullerene Y@C82
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An Early Jurassic jumping frog
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Life Sciences, Biology, Zoology +11
Giant motion of La atom inside C82 cage
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