Measuring asphaltenes and resins, and dipole moment in petroleum fluids

Abstract

Abstract A petroleum fluid can be divided into three types of species: asphaltenes, resins, and oils. Asphaltenes and resins are polar, while the rest of the so‐called oils are either nonpolar or mildly polar. The interaction among these species strongly affect asphaltene precipitation from petroleum fluids. Different measuring methods for asphaltenes in a petroleum fluid give similar results, but different results for the resin content of a petroleum fluid. In addition to the amount affecting precipitation, the polarity of asphaltenes and resins affects precipitation strongly. The Onsager formulation of dipolar moments was used to measure the dipole moment of asphaltenes, resins and the oil species from eight different petroleum fluids from various parts of the world. The dipole moment, a measure of polarity, for resins was measured in this work for the first time. Results showed that resin separated from a petroleum fluid by propane is part of the total resin. Adsorption methods, however, give the total amount of resins. For a given petroleum fluid, asphaltenes had a higher dipole moment than resins. However, resins from one petroleum fluid can have a higher dipole moment than asphaltenes from another petroleum fluid.