Physical Review · 1968 · 139 citations · 30 references
Natural SciencesPhysicsCondensed Matter PhysicsQuantum MechanicsSpectroscopyBubble DynamicsElectronic Excited StatesElectronic StructureMolecular Excited StatesStates Of MatterAtomic Line ShapesExcited Electronic StatesExcited State CalculationsExcited-state ConfigurationsJahn-teller DistortionJahn-teller EffectsOptical PropertiesOscillator Strengths
A calculation of the optical properties of electronic bubbles in liquid helium is presented. Making use of the measured well depth and surface tension, we have computed the electronic states as a function of bubble size and have calculated the configuration coordinate diagrams, transition energies, oscillator strengths, lifetimes, cross sections, line shapes, linewidths, and estimated the magnitude of the static Jahn-Teller effect in an excited state. The dependence on pressure is considered for some of these quantities from 0-20 atm.
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