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Molekulares Verdrillungsvermögen von Kohlenhydrat-Derivaten
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1988
Year
Crystal StructureEngineeringOrganic ChemistryChemistrySingle Chiral CentersChemical DerivativeCrystal FormationBiophysicsMolecular SolidLiquid Crystalline PhaseBiochemistryCrystal MaterialCrystallographyCrystal Structure DesignNatural SciencesApplied PhysicsHelix InversionDerivative (Chemistry)Molekulares Verdrillungsvermögen
For the first time carbohydrate derivatives were systematically studied as doping material for a liquid crystalline phase. These compounds can exhibit a large twisting power. It may be controlled by the configurations of single chiral centers. Thus, a series of phenomena are realized in the cholesteric phase such as helix inversion, large or small temperature dependencies of the pitch, as well as broad blue phases.