Dalton Transactions · 2012 · 64 citations · 26 references
Natural SciencesChemistryPhysicsMagnetic MaterialsOrganometallic ChemistrySpectroscopyFluorescence SpectroscopyInorganic SpectroscopyLuminescent MaterialsMagnetism Of Inorganic CompoundsEmission SpectrumMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesMolecular ChromophoresMolecular MagnetismSingle-molecule MagnetismSingle-molecule Magnets
An assemblage of a Tb(III) ion and two mononuclear [Zn(II)(L)] complexes as antenna chromophores (H(2)L: Schiff base ligand) afforded a luminescent single-molecule magnet. The f-f emission spectrum had partially resolved fine structure which provides detailed information on the magnetic anisotropy of the (7)F(6) ground multiplet of the Tb(III) ion.
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Jihyun An, Chad M. Shade, Demetra A. Chengelis-Czegan et al. · Journal of the American Chemical Society · 2011 · 621 citations