Linewidth and Temperature Shift of the <i>R</i> Lines in Ruby

Abstract

Improved experimental data have been obtained between 20° and 350°K for the widths and temperature shifts of the R lines in ruby. Above 77°K the results can be accurately described in terms of Raman scattering of Debye-model phonons. There is no evidence for measurable contributions to the widths and shifts from direct processes involving emission or absorption of a single resonant phonon. Below 77°K the principal contributions are from crystal inhomogeneities.