Elucidation of the Mechanism in Fluorine-Free Prepared YBa₂Cu₃O_7−δ Coatings

Abstract

In this work, the reaction mechanism used in the preparation of fluorine-free superconducting YBa(2)Cu(3)O(7-delta) (YBCO) was investigated. To determine which precursor interactions are dominant, a comprehensive thermal analysis (thermogravimetric analysis-differential thermal analysis) study was performed. The results suggest that a three step reaction mechanism, with a predominant role for BaCO(3), is responsible for the conversion of the initial state to the superconducting phase. In the presence of CuO, the decarboxylation of BaCO(3) is kinetically favored with the formation of BaCuO(2) as a result. BaCuO(2) reacts with the remaining CuO to form a liquid which ultimately reacts with Y(2)O(3) in a last step to form YBCO. High temperature X-ray diffraction experiments confirm that these results are applicable for thin film synthesis prepared from an aqueous fluorine-free sol-gel precursor.