Publication | Closed Access
HYPOCHROMISM OF VINYLPOLYMERS WITH LARGE PENDANT π-ELECTRON SYSTEMS
59
Citations
11
References
1974
Year
Materials ScienceBlock Co-polymersEngineeringNatural SciencesPolymer ScienceResponsive PolymersApplied PhysicsElectronic InteractionsMonomeric ModelsPolymer PhysicPolymer ChainPolymer CharacterizationChemistryQuantum ChemistryPolymer AnalysisMolecular PolymerPolymer ChemistryPolymers
Abstract The absorption spectra of vinylpolymers with large pendant π-electron systems show the hypochromism, change in the structure of the 1Bb or 1Ba band, and lower (or higher)-frequency shift in comparison with the spectra of the monomeric models. These arise from some electronic interactions between neighboring chromophores in a polymer chain.
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