Concepedia

Consecutive Intramolecular Hydroamination/Asymmetric Transfer Hydrogenation under Relay Catalysis of an Achiral Gold Complex/Chiral Brønsted Acid Binary System

Zhi‐Yong Han, Han Xiao, Xiaohua Chen, Liu‐Zhu Gong

Journal of the American Chemical Society · 2009 · 371 citations · 32 references

DOI

Concepts

Abstract

Consecutive hydroamination/asymmetric transfer hydrogenation under relay catalysis of an achiral gold complex/chiral Brønsted acid binary system has been described for the direct transformation of 2-(2-propynyl)aniline derivatives into tetrahydroquinolines with high enantiomeric purity.

References

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