Segregation of indium in InGaAs/GaAs quantum wells grown by vapor-phase epitaxy

Abstract

Distribution of indium atoms in structures which contained double InGaAs/GaAs quantum wells and were grown by vapor-phase epitaxy from metal-organic compounds was studied. Experimental indium-concentration profiles were obtained using Auger electron spectroscopy. A model of growth with allowance made for indium segregation and a model for the Auger profiling were used in the calculations of profiles. Fitting calculated profiles to experimental ones made it possible to estimate the activation energies for In-Ga exchange in the context of a kinetic model for segregation. These energies are found to be somewhat higher than those that are well known for molecular-beam epitaxy, which is related to stabilization of the growth surface by hydrogen atoms in a vapor-phase reactor.