Physical Review Letters · 1993 · 288 citations · 16 references
Quantum LiquidEngineeringLiquid-liquid FlowFluid MechanicsPolar LiquidChemistrySimple LiquidSoft MatterLiquid-vapor CoexistenceDipolar Hard-sphere FluidPhase SeparationPhysicsDispersive EnergyPhysical ChemistryInterfacial PhenomenonNatural SciencesApplied PhysicsFluid-solid InteractionPolar Science
The study reports computer simulations of the phase behavior of dipolar (ferro‑) fluids. The authors use a model that independently varies dispersive and dipolar interactions in computer simulations. Simulations show that a minimum dispersive energy is required for liquid–vapor coexistence; below this threshold dipolar hard‑sphere fluids form dipole chains and do not phase separate.
We report computer simulations of the phase behavior of dipolar (ferro-) fluids. We consider a model in which the dispersive interactions can be varied independently from the dipolar (magnetic) interactions. The simulation results show that a minimum amount of dispersive energy is required to observe liquid-vapor coexistence. If the dispersive energy is below this threshold, as for example in the dipolar hard-sphere fluid, the system forms chains of dipoles aligning nose to tail. Our simulations did not give any evidence that these ``polymerlike'' systems phase separate into a liquid and vapor phase.
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Phase Transition for a Hard Sphere System
B. J. Alder, T. E. Wainwright · The Journal of Chemical Physics · 1957 · 2.5K citations
Computer simulations in the Gibbs ensemble
Berend Smit, Ph. De Smedt, Daan Frenkel · Molecular Physics · 1989 · 350 citations · Full text