Concepedia

A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

Chuanqiang Li, Wenge Qiu, Wei Shi, Haibin Song, Guangmei Bai, Hong He, Jian Li, Michael J. Zaworotko

CrystEngComm · 2012 · 37 citations · 63 references

DOI

Concepts

Abstract

A flexible ligand with two 1,3-benzenedicarboxylate units has been used to construct a microporous metal–organic framework with pcu topology based on supramolecular building blocks (SBBs). The obtained Cu(II) MOF exhibits a noticeable CO2 adsorption hysteresis and a comparable methane adsorption capacity at room temperature.

References

63

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Anthony L. Spek · Journal of Applied Crystallography · 2003 · 13.9K citations · Full text

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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

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Modular Chemistry:  Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks

Mohamed Eddaoudi, David B. Moler, Hailian Li et al. · Accounts of Chemical Research · 2001 · 5.2K citations

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Hiroyasu Furukawa, Nakeun Ko, Yong Bok Go et al. · Science · 2010 · 3.9K citations

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BYPASS: an effective method for the refinement of crystal structures containing disordered solvent regions

P. van der Sluis, Anthony L. Spek · Acta Crystallographica Section A Foundations of Crystallography · 1990 · 3.8K citations

, , +15