Concepedia

Ruthenium-catalyzed oxidation of alcohols by bromate in water

Zongmin Hu, Li Ma, Jianhui Xie, Hongxia Du, William W. Y. Lam, Tai‐Chu Lau

New Journal of Chemistry · 2013 · 14 citations · 45 references

DOI

Concepts

Abstract

The polypyridylruthenium(II) complex, cis-[Ru(2,9-Me2phen)2(OH2)2]2+, is a highly efficient catalyst for the oxidation of alcohols to carbonyl products in water using sodium bromate (NaBrO3) as the terminal oxidant. Excellent conversions and yields are readily achieved at room temperature.

References

45

Bromate Formation during Ozonization of Bromide-Containing Waters: Interaction of Ozone and Hydroxyl Radical Reactions

Urs von Gunten, Juerg. Hoigne · Environmental Science & Technology · 1994 · 582 citations · Full text

, , +16

Ozonation of bromide-containing waters: kinetics of formation of hypobromous acid and bromate

Werner R. Haag, Juerg. Hoigne · Environmental Science & Technology · 1983 · 549 citations

, , +10

Supported Ruthenium Catalyst for the Heterogeneous Oxidation of Alcohols with Molecular Oxygen

Kazuya Yamaguchi, Noritaka Mizuno · Angewandte Chemie International Edition · 2002 · 502 citations · Full text

, , +17

Creation of a Monomeric Ru Species on the Surface of Hydroxyapatite as an Efficient Heterogeneous Catalyst for Aerobic Alcohol Oxidation

Kazuya Yamaguchi, Kohsuke Mori, Tomoo Mizugaki et al. · Journal of the American Chemical Society · 2000 · 456 citations

, , +15

Efficient Heterogeneous Aerobic Oxidation of Amines by a Supported Ruthenium Catalyst

Kazuya Yamaguchi, Noritaka Mizuno · Angewandte Chemie International Edition · 2003 · 373 citations

, , +12