Angewandte Chemie International Edition · 2002 · 502 citations · 2 references
Natural SciencesChemical EngineeringChemistryCatalysisInorganic ChemistryReaction EngineeringCatalyst DesignCatalyst PreparationCatalytic MaterialsCatalytic MechanismsOxidation ReactionsSupported CatalystsAlcohol OxidationCatalyst RecyclingCatalytic ActivityHeterogeneous Catalyst PreparationHeterogeneous OxidationOxidationOxidation Of Alcohols To Carbonyl CompoundsSupported Oxidation Catalysts
Round and round it goes! A supported ruthenium catalyst, easily prepared by treatment of RuCl3 with γ-Al2O3, is an efficient heterogeneous catalyst for the oxidations of alcohols with 1 atm of molecular oxygen or air without any additives (see scheme). The spent catalyst was recyclable without an appreciable loss of the catalytic activity and selectivity for the oxidation.
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Oxidations in Organic Chemistry
Analytical Chemistry · 1991 · 709 citations