Concepedia

Nickel-Catalyzed Arylcyanation of Alkynes

Yoshiaki Nakao, Shinichi Oda, Tamejiro Hiyama

Journal of the American Chemical Society · 2004 · 251 citations · 14 references

DOI

Concepts

Abstract

A nickel catalyst coordinated by trimethylphosphine is found to effect the addition reaction of Ar-CN bonds in aromatic nitriles across alkynes to give rise to various beta-arylalkenenitriles.

References

14

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.sigma.-Aryl compounds of nickel, palladium, and platinum. Synthesis and bonding studies

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Kinetics, Thermodynamics, and Effect of BPh<sub>3</sub>on Competitive C−C and C−H Bond Activation Reactions in the Interconversion of Allyl Cyanide by [Ni(dippe)]

N.M. Brunkan, Donna M. Brestensky, William D. Jones · Journal of the American Chemical Society · 2004 · 187 citations

Nickel(0)-catalyzed synthesis of substituted phenols from cyclobutenones and alkynes

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The <i>Ansa</i> Effect in Permethylmolybdenocene Chemistry:  A [Me<sub>2</sub>Si] <i>Ansa</i> Bridge Promotes Intermolecular C−H and C−C Bond Activation

David G. Churchill, Jun Ho Shin, T. Hascall et al. · Organometallics · 1999 · 131 citations

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