Concepedia

The synthesis and crystal structure of a new polyoxovandium cluster anion: [As III 8V IV 14O42(0.5H2O)]4?

Guohe Huan, Mark A. Greaney, Allan J. Jacobson

Journal of the Chemical Society Chemical Communications · 1991 · 73 citations · 5 references

DOI

Concepts

Abstract

The dark-brown compound [N(Me)4]4[AsIII8VIV14O42(0.5H2O)] containing a spherical anion [AsIII8VIV14O42(0.5H2O)]4– containing condensed VO5 square pyramids and As 2O5 units, is synthesized hydrothermally from As2O3, V2O5 and (Me)4NOH and structurally characterized by X-ray diffraction.

References

5

Synthesis and characterization of a soluble oxide inclusion complex, [CH3CN.cntnd.(V12O324-)]

Victor W. Day, W. G. Klemperer, Omar M. Yaghi · Journal of the American Chemical Society · 1989 · 210 citations

, , +10

A Novel Heterocluster with <i>D</i><sub>3</sub>‐Symmetry Containing Twenty‐One Core Atoms: [AsVO<sub>42</sub>(H<sub>2</sub>O)]<sup>6⊖</sup>

Achim Müller · Angewandte Chemie International Edition in English · 1988 · 204 citations

, , +11

Topologically Interesting Cages for Negative Ions with Extremely High “Coordination Number”: An Unusual Property of V‐O Clusters

Achim Müller, Ralf Rohlfing, Erich Krickemeyer · Angewandte Chemie International Edition in English · 1990 · 195 citations

, , +13

Existence and structure of the molecular ion 18-vanadate(IV)

Garrett K. Johnson, E. O. Schlemper · Journal of the American Chemical Society · 1978 · 147 citations

, , +8

Spherical Mixed‐Valence [V<sub>15</sub>O<sub>36</sub>]<sup>5⊖</sup>, an Example from an Unusual Cluster Family

Achim Müller, Erich Krickemeyer, Heinz‐Jürgen Walberg et al. · Angewandte Chemie International Edition in English · 1987 · 133 citations

, , +14