Langmuir · 2005 · 469 citations · 17 references
EngineeringChemical EngineeringMaterials ScienceMicrofabricationPolymer ChemistryPolymer EngineeringMicrofluidic Device FabricationMicrofluidic DevicesMicrofluidic SystemsMicrofluidic TransportMicrofluidicsPolymer ProcessingDroplet MicrofluidicsMicrochannel DesignMicrofluidic Device DesignMicrofluidic Droplet GenerationMicrofluidic FabricationMicroparticlesPolymeric MicroparticlesShape-controlled Synthesis
The controlled synthesis of nonspherical microparticles using microfluidics processing is described. Polymer droplets, formed by shearing a photopolymer using a continuous water phase at a T-junction, were constrained to adopt nonspherical shapes by confining them using appropriate microchannel geometries. Plugs were obtained by shearing the polymer phase at low shear rates, while disks were obtained by flattening droplets using a channel of low height. The nonspherical shapes formed were permanently preserved by photopolymerizing the constrained droplets in situ using ultraviolet light. Monodisperse plugs and disks of different lengths and diameters were obtained by varying the flow rates of the two phases.
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Dynamic Pattern Formation in a Vesicle-Generating Microfluidic Device
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Droplet formation in a microchannel network
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