Publication | Closed Access
Insights into the Mechanism of the Negishi Reaction: ZnRX versus ZnR<sub>2</sub>Reagents
100
Citations
7
References
2007
Year
EngineeringBiochemistryReactive Nitrogen SpecieNatural SciencesNegishi ReactionsMolecular BiologyDifferent IsomerOrganic ChemistryDifferent EvolutionsChemistryHeterocycle ChemistryRedox BiologyNitrosative StressBiomolecular EngineeringNegishi Reaction
The observation that their transmetalations with trans-[PdRfCl(PPh3)2] (Rf = fluoroaryl) give stereoselectively a different isomer of [PdRfMe(PPh3)2] suggests that Negishi reactions with ZnRX or ZnR2 could show very different evolutions.
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