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The First Structurally Characterized Aluminum Compound with Two SH Groups: [LAl(SH)<sub>2</sub>] (L = N(Ar)C(Me)CHC(Me)N(Ar), Ar = 2,6-<i>i</i>-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) and the Catalytic Properties of the Sulfur P(NMe<sub>2</sub>)<sub>3</sub> System
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Citations
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References
2003
Year
Materials ScienceInorganic ChemistryEngineeringSh GroupsSulfur PAluminum LalStructure ElucidationOrganometallic CatalysisCatalysisMain Group ChemistryChemistryHydrogenCatalytic PropertiesHydrogen SulfideInorganic SynthesisInorganic Compound
Surprisingly stable is the bis(hydrogen sulfide) of aluminum LAl(SH)(2) with two terminal arranged SH groups. The insertion of sulfur into the Al-H bonds is catalyzed by SP(NMe(2))(3). A possible mechanism is discussed.
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