Concepedia

Aerobic Epoxidation of Olefins Catalyzed by Cobalt(II) Complex Using Propionaldehyde Diethyl Acetal as a Reductant

Teruaki Mukaiyama, Kiyotaka Yorozu, Toshihiro Takai, Tohru Yamada

Chemistry Letters · 1993 · 44 citations · 3 references

DOI

Concepts

Abstract

Abstract In the presence of bis(3-methyl-2,4-pentanedionato)cobalt(II) complex catalyst, various trisubstituted olefins are smoothly monooxygenated into the corresponding epoxides in high yields under neutral conditions by the combined use of molecular oxygen and propionaldehyde diethyl acetal.

References

3

Direct Epoxidation of Olefins Catalyzed by Nickel(II) Complexes with Molecular Oxygen and Aldehydes

Tohru Yamada, Toshihiro Takai, Oliver Rhode et al. · Bulletin of the Chemical Society of Japan · 1991 · 171 citations · Full text

, , +13

Ozonolysis of Acetals. (<i>1</i>) Ester Synthesis, (<i>2</i>) THP Ether Cleavage, (<i>3</i>) Selective Oxidation of β-Glycoside, (<i>4</i>) Oxidative Removal of Benzylidene and Ethylidene Protecting Groups

Pierre Deslongchamps, Claude Moreau · Canadian Journal of Chemistry · 1971 · 98 citations

, , +9

Catalytic Oxidation–Reduction Hydration of Olefin with Molecular Oxygen in the Presence of Bis(1,3-diketonato)cobalt(II) Complexes

Koji Kato, Tohru Yamada, Toshihiro Takai et al. · Bulletin of the Chemical Society of Japan · 1990 · 89 citations · Full text

, , +10