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Ozonolysis of Acetals. (<i>1</i>) Ester Synthesis, (<i>2</i>) THP Ether Cleavage, (<i>3</i>) Selective Oxidation of β-Glycoside, (<i>4</i>) Oxidative Removal of Benzylidene and Ethylidene Protecting Groups
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1971
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Advanced Oxidation ProcessEngineeringOrganic ChemistryChemistryChemical DerivativeChemical EngineeringThp Ether CleavageBenzylidene DerivativesEster SynthesisStereoselective SynthesisSelective OxidationBiochemistryCatalysisNatural Product SynthesisEnantioselective SynthesisTetrahydropyranyl EthersAlkene MetathesisNatural SciencesCorresponding Esters
Ozone reacts very smoothly with acetals to give the corresponding esters. Tetrahydropyranyl ethers, β-glycopyranosides, ethylidene, or benzylidene derivatives are also oxidized whereas the α-glycopyranosides are inert.