Concepedia

One-pot synthesis of 2,3-substituted benzo[b]thiophenes via Cu(<scp>i</scp>) catalysed intramolecular cyclisation from dithioesters

Nagarakere C. Sandhya, Kebbahalli N. Nandeesh, Kanchugarakoppal S. Rangappa, Sannaiah Ananda

RSC Advances · 2015 · 18 citations · 48 references

DOI

Concepts

Abstract

The novel route involves CuI catalyzed C–S bond formation using dithioesters. This approach is valuable for synthesis of rolaxifene analogues.

References

48

A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols

Manuel A. Fernández‐Rodríguez, Qilong Shen, John F. Hartwig · Journal of the American Chemical Society · 2006 · 707 citations

, , +13

Iron‐Catalyzed S‐Arylation of Thiols with Aryl Iodides

Arkaitz Correa, Mónica Carril, Carsten Bolm · Angewandte Chemie International Edition · 2008 · 548 citations

, , +10

Efficacy of Raloxifene on Vertebral Fracture Risk Reduction in Postmenopausal Women with Osteoporosis: Four-Year Results from a Randomized Clinical Trial

Pierre D. Delmas, Kristine E. Ensrud, Jonathan D. Adachi et al. · The Journal of Clinical Endocrinology & Metabolism · 2002 · 541 citations · Full text

, , +14

A β-Keto Ester as a Novel, Efficient, and Versatile Ligand for Copper(I)-Catalyzed C−N, C−O, and C−S Coupling Reactions

Xin Lv, Weiliang Bao · The Journal of Organic Chemistry · 2007 · 447 citations

, , +15

The First Phosphine Oxide Ligand Precursors for Transition Metal Catalyzed Cross-Coupling Reactions: C−C, C−N, and C−S Bond Formation on Unactivated Aryl Chlorides

George Y. Li · Angewandte Chemie International Edition · 2001 · 420 citations

, , +15