A one-pot synthesis of conjugated dienynes by palladium-mediated three component cross-coupling reaction

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate

Yasuo Hatanaka, Tamejiro Hiyama · The Journal of Organic Chemistry · 1988 · 644 citations

Halogenation, Chemical Engineering, Cross-coupling Reaction +10

Novel and convenient method for the stereo- and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes

Norio Miyaura, Kinji Yamada, Hiroshi Suginome et al. · Journal of the American Chemical Society · 1985 · 513 citations

Cross-coupling Reaction, Engineering, Donut Icon +14

Stereospecific palladium-catalyzed coupling reactions of vinyl iodides with acetylenic tin reagents

J. K. Stille, James H. Simpson · Journal of the American Chemical Society · 1987 · 212 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +10

Alkenylfluorosilanes as widely applicable substrates for the palladium-catalyzed coupling of alkenylsilane/fluoride reagents with alkenyl iodides

Yasuo Hatanaka, Tamejiro Hiyama · The Journal of Organic Chemistry · 1989 · 142 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +13